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[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61?(4)°], with the distortion related to a short intra-molecular Au?O contact [2.988?(3)?Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H?? inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2979546 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100519 Pt 6

The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61 (4)°], with the distortion related to a short intra-molecular Au⋯O contact [2.988 (3) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H⋯π inter-actions. ...[more]

PMID: 21579308

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