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(?-Benzene){2-[2-(tert-butyl-sulfan-yl)phenyl]pyridine-?N,S}chlorido-ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an ?(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S-Ru-N bite angle is 86.76?(9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8?(2)°. The unit cell contains two pairs of racemic diastereomers with (S(Ru),S(S)) and (R(Ru),R(S)) configurations, in which the tert-butyl group on the coordin-ated S atom is distant from the ?(6)-benzene ligand.

SUBMITTER: Hirotsu M

PROVIDER: S-EPMC3050383 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(η-Benzene){2-[2-(tert-butyl-sulfan-yl)phenyl]pyridine-κN,S}chlorido-ruthenium(II) hexa-fluorido-phosphate.

Hirotsu Masakazu M Yogi Akira A Kinoshita Isamu I

Acta crystallographica. Section E, Structure reports online 20101211 Pt 1

In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl-sulfan-yl)phen-yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S-Ru-N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell ...[more]

PMID: 21522582

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